Molecular Orbital Theory - Detailed Explanation with Tips and Tricks
In MO theory, molecular orbitals form by the overlap of atomic orbitals. Atomic orbital energy correlates with electronegativity, as electronegative atoms hold electrons more tightly, lowering their energies. MO modeling is only valid when the atomic orbitals have comparable energy; when the energies differ greatly, the bonding mode becomes ionic. A second condition for overlapping atomic orbitals is that they have identical symmetry.
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